I have no idea what you mean with manifestation, I believe that it can all be put down under effect. Note that Heizen, Gritz, Wolke and Sprenger are Canon.
Name of Spell: Heizen
Effects: This technique creates a transparent, rectangular beam of energy from the silver tubes which slices through the opponent.
Incantation: "Feel the wrath of battle and accept this sacred chalice - Heating!"
Name of Spell: Gritz
Effects: This technique forms a man-sized pentagonal Quincy cross which envelops its target.
Incantation: "A silver rod strikes the five-fingered stone bed - Quintuple Restraining Frames!"
Name of Spell: Wolke
Effects: This technique uses a silver tube to create a large blast. While it may not be intended for use as such, Uryū uses it to cushion the impact of a fall.
Incantation: "Tilt the goblet to the west - Emerald Grail!"
Name of Spell: Sprenger
Effects: This technique uses five Seele Schneiders to create a pentagon-shaped seal which, when activated, causes a massive explosion within its borders. When an object or a person stands within the middle of the Pentagon the placement of the fifth Seele Schneider can trap them by wrapping and binding their legs to the ground with dense spirit particles. The Seele Schneiders function as accumulators, gathering the necessary amount of spirit particles to create the explosion. The liquid inside a silver tube acts as the trigger. The preparations for the technique combined with the charging time for the Seele Schneiders make its use in battle impractical unless the user has a partner that can stall to buy time, or has enough strength to create the formation while under attack
Incantation: None
Name of Spell: Metamorphosa
Effects: This technique uses a silver tube to change the appearance of the user permanently.
Incantation: "Seek the beauty from within - Black Rose!"
Name of Spell: Nebel
Effects: This technique uses silver tube to release reiatsu as a silver fog, obscuring the area. Eve is still able to see through the fog.
Incantation: "Through the darkness of the heart the eye of the righteous can still see - Nebulal!"
Name of Spell: Eisenwall
Effects: This technique uses a silver tube like wall of fire forming a solid amount of spiritual particles in a silver wall barrier. The wall
Incantation: Name of Spell: Spinnennetz
Effects: This technique uses a silver tubes to erupt reiatsu in a web to pin a target to a surface.
Incantation: "There is no way to move - Widow!"